The incorporation of three terdentate 2,6-bis-triazolyl-pyridine units on a calix[4]arene gives a preorganized lipophilic ligand with enhanced efficiency in binding trivalent actinides over lanthanides. Combined time-resolved laser-induced fluorescence spectroscopy, and 1D and 1H-15N HMQC NMR investigations allowed to propose the structures of the complexes and to provide insights into the actinide selectivity.
A preorganized triarmed bis-triazolylpyridine-calix[4]arene with high affinity and selectivity for minor actinides for nuclear waste treatment / Baccelli, D; Stracke, J; Gullo, Mc; Wessling, P; Grivas, S; Rispoli, F; Volpi, S; Mele, A; Geist, A; Panak, Pj; Sansone, F; Sittel, T; Macerata, E; Casnati, A. - In: CHEMICAL COMMUNICATIONS. - ISSN 1364-548X. - 61:73(2025), pp. 13968-13971. [10.1039/d5cc02948a]
A preorganized triarmed bis-triazolylpyridine-calix[4]arene with high affinity and selectivity for minor actinides for nuclear waste treatment
Baccelli, D;Gullo, MC;Rispoli, F;Volpi, S;Mele, A;Sansone, F;Casnati, A
2025-01-01
Abstract
The incorporation of three terdentate 2,6-bis-triazolyl-pyridine units on a calix[4]arene gives a preorganized lipophilic ligand with enhanced efficiency in binding trivalent actinides over lanthanides. Combined time-resolved laser-induced fluorescence spectroscopy, and 1D and 1H-15N HMQC NMR investigations allowed to propose the structures of the complexes and to provide insights into the actinide selectivity.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
