Sequential Strategies to Trigger Mild Dearomative Diels-Alder Cyclizations

Dihydronaphthalenes are present in several functional molecules, but their assembly is challenging. However, a sequential strategy can induce the key annullation of an alkyne with a vinylarene under mild conditions. Products form in good yields, with ample functional tolerance via domino nucleophilic substitution and dearomative Diels-Alder and ene reactions. DFT modeling data show that alkali cations are crucial to ensure a smooth dearomative cyclization on the in situ generated intermediates.

The managerial role of healthcare professionals in public hospitals: a time-driven analysis of their activities

Background: New Public Management theory affected reforms of public sectors worldwide. In Italy, an important reform of the healthcare sector changed the profile of public hospitals, creating new management related positions in 1992. The reform defined the role of the clinician-manager: a hybrid figure, in charge of managing an entire unit. This paper aims to investigate how much clinician-managers feel like managers and how much they still feel like professionals, using time as a driver to c...

La gestione del cambiamento organizzativo. Un confronto tra le aspettative dell’organizzazione ed il punto di vista dei lavoratori nell’ottica della consulenza aziendale

Lo scopo di questo lavoro è analizzare l’attuale letteratura sul cambiamento organizzativo, mettendo in luce gli aspetti che possono essere utilizzati nella consulenza aziendale per supportare, da un lato, i processi organizzativi e, dall’altro, i lavoratori nelle fasi di cambiamento. Sono stati selezionati articoli dal 2014 al 2019; le tematiche esaminate rispetto alla gestione organizzativa riguardano la comunicazione aziendale e la leadership, mentre il job crafting è stato analizzato dal ...

A Contribution to the Italian Validation of the Manhardt’s Work Values Inventory