Mechanochemical synthesis is an attractive preparative method that combines a green approach with versatility, efficiency, and rapidity of reaction. However, it often yields microcrystalline materials, and their small crystal size is a major hindrance to structure elucidation with conventional single-crystal or powder X-ray diffraction methods. This work presents the novel approach of combining mechanochemistry with electron diffraction techniques to elucidate the crystal structure of metal−organic compounds of zinc(II) and copper(II) with 2,6-pyridinedicarboxylic acid and 4,4′-bipyridine.

Combined Approach of Mechanochemistry and Electron Crystallography for the Discovery of 1D and 2D Coordination Polymers / Marchetti, Danilo; Guagnini, Francesca; Lanza, Arianna E.; Pedrini, Alessandro; Righi, Lara; Dalcanale, Enrico; Gemmi, Mauro; Massera, Chiara. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 21(2021), pp. 6660-6664. [10.1021/acs.cgd.1c01058]

Combined Approach of Mechanochemistry and Electron Crystallography for the Discovery of 1D and 2D Coordination Polymers

Marchetti, Danilo;Guagnini, Francesca;Pedrini, Alessandro;Righi, Lara;Dalcanale, Enrico;Massera, Chiara
2021

Abstract

Mechanochemical synthesis is an attractive preparative method that combines a green approach with versatility, efficiency, and rapidity of reaction. However, it often yields microcrystalline materials, and their small crystal size is a major hindrance to structure elucidation with conventional single-crystal or powder X-ray diffraction methods. This work presents the novel approach of combining mechanochemistry with electron diffraction techniques to elucidate the crystal structure of metal−organic compounds of zinc(II) and copper(II) with 2,6-pyridinedicarboxylic acid and 4,4′-bipyridine.
Combined Approach of Mechanochemistry and Electron Crystallography for the Discovery of 1D and 2D Coordination Polymers / Marchetti, Danilo; Guagnini, Francesca; Lanza, Arianna E.; Pedrini, Alessandro; Righi, Lara; Dalcanale, Enrico; Gemmi, Mauro; Massera, Chiara. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 21(2021), pp. 6660-6664. [10.1021/acs.cgd.1c01058]
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11381/2903403
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