We report the synthesis and characterization of novel triphosphine calix[6]arene ligands. These supramolecular wheels, with recognition features governed by the hydrogen-bonding domain, were employed to synthesize multitasking trinuclear gold(I) complexes as a new platform for the synthesis of interwoven (pseudo)rotaxane species. In parallel, the multivalent, metal-bonded upper rim displayed catalytic features promoting highly selective gold-catalyzed cycloisomerization reactions of 1,6-enynes.

Merging Molecular Recognition and Gold(I) Catalysis with Triphoscalix[6]arene Ligands / Cera, G.; Giovanardi, G.; Secchi, A.; Arduini, A.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 27:40(2021), pp. 10261-10266. [10.1002/chem.202101323]

Merging Molecular Recognition and Gold(I) Catalysis with Triphoscalix[6]arene Ligands

Cera G.
;
Secchi A.
;
Arduini A.
2021-01-01

Abstract

We report the synthesis and characterization of novel triphosphine calix[6]arene ligands. These supramolecular wheels, with recognition features governed by the hydrogen-bonding domain, were employed to synthesize multitasking trinuclear gold(I) complexes as a new platform for the synthesis of interwoven (pseudo)rotaxane species. In parallel, the multivalent, metal-bonded upper rim displayed catalytic features promoting highly selective gold-catalyzed cycloisomerization reactions of 1,6-enynes.
2021
Merging Molecular Recognition and Gold(I) Catalysis with Triphoscalix[6]arene Ligands / Cera, G.; Giovanardi, G.; Secchi, A.; Arduini, A.. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 27:40(2021), pp. 10261-10266. [10.1002/chem.202101323]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2895733
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