Proximal 1,2-bis-demethylation of tetramethoxy-p-t-butylcalix[4]arene 1 has been achieved for the first time by Ti(IV)-assisted reaction, which allows the synthesis of a new type of calixarene-based bis-crown ether.
Selective 1,2-functionalization of calix[4]arenes at the lower rim. Synthesis of a new type of bis-calixcrown ether / Arduini, Arturo; Casnati, Alessandro; L., Dodi; Pochini, Andrea; Ungaro, Rocco. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - (1990), pp. 1597-1598. [10.1039/c39900001597]
Selective 1,2-functionalization of calix[4]arenes at the lower rim. Synthesis of a new type of bis-calixcrown ether
ARDUINI, Arturo;CASNATI, Alessandro;POCHINI, Andrea;UNGARO, Rocco
1990-01-01
Abstract
Proximal 1,2-bis-demethylation of tetramethoxy-p-t-butylcalix[4]arene 1 has been achieved for the first time by Ti(IV)-assisted reaction, which allows the synthesis of a new type of calixarene-based bis-crown ether.File in questo prodotto:
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