We report a combined spectroscopic and structural study of polymorphism of 1,1,4,4-tetraphenyl-1,3- butadiene (TPB) blue luminescent crystals. We have identified two polymorphs, which can be grown by crystallization of the vapor. The first, R-TPB, has the monoclinic noncentrosymmetric structure (P21, two molecules per unit cell), whose lattice parameters have already been reported in the literature. The second, β-TPB, is a new polymorph, monoclinic centrosymmetric (P21/c, four molecules per unit cell). The previously reported triclinic structure, γ-TPB, has not been identified in samples grown by the physical vapor transport method. The effects of the different molecular configuration and packing of Rand β-TPB on Raman scattering, IR, and UV-vis optical properties are discussed.
Spectroscopic and Structural Characterization of Two Polymorphsof 1,1,4,4-Tetraphenyl-1,3-butadiene / Girlando, Alberto; Ianelli, Sandra; I., Bilotti; A., Brillante; R. G., Della Valle; E., Venuti; M., Campione; S., Mora; L., Silvestri; P., Spearman; S., Tavazzi. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 10:(2010), pp. 2752-2758. [10.1021/cg100253k]
Spectroscopic and Structural Characterization of Two Polymorphsof 1,1,4,4-Tetraphenyl-1,3-butadiene
GIRLANDO, Alberto
;IANELLI, Sandra;
2010-01-01
Abstract
We report a combined spectroscopic and structural study of polymorphism of 1,1,4,4-tetraphenyl-1,3- butadiene (TPB) blue luminescent crystals. We have identified two polymorphs, which can be grown by crystallization of the vapor. The first, R-TPB, has the monoclinic noncentrosymmetric structure (P21, two molecules per unit cell), whose lattice parameters have already been reported in the literature. The second, β-TPB, is a new polymorph, monoclinic centrosymmetric (P21/c, four molecules per unit cell). The previously reported triclinic structure, γ-TPB, has not been identified in samples grown by the physical vapor transport method. The effects of the different molecular configuration and packing of Rand β-TPB on Raman scattering, IR, and UV-vis optical properties are discussed.File | Dimensione | Formato | |
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