The first example of a calix[4]arene amino acid is reported. It allowed the synthesis of the novel N,Clinked peptidocalix[4]arenes which self-assemble in low-polarity media to give chiral dimeric capsules held together by an antiparallel â-sheetlike hydrogen-bonding motif.
Chiral dimeric capsules from N,C-linked peptidocalix[4]arenes self-assembled through an antiparallel b-sheetlike motif / Sansone, Francesco; Baldini, Laura; Casnati, Alessandro; E., Chierici; Faimani, Giovanni; Ugozzoli, Franco; Ungaro, Rocco. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 126:(2004), pp. 6204-6205. [10.1021/ja031511z]
Chiral dimeric capsules from N,C-linked peptidocalix[4]arenes self-assembled through an antiparallel b-sheetlike motif
SANSONE, Francesco;BALDINI, Laura;CASNATI, Alessandro;FAIMANI, Giovanni;UGOZZOLI, Franco;UNGARO, Rocco
2004-01-01
Abstract
The first example of a calix[4]arene amino acid is reported. It allowed the synthesis of the novel N,Clinked peptidocalix[4]arenes which self-assemble in low-polarity media to give chiral dimeric capsules held together by an antiparallel â-sheetlike hydrogen-bonding motif.| File | Dimensione | Formato | |
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JACS04 capsule SI.pdf
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