Two N-alkyloxy-N '-phenylimidazolium proligands and the corresponding platinum(II) cyclometalated N-alkyloxyimidazol-2-ylidene complexes with beta-diketonate auxiliary ligands, [(C-NOHC<^>C*)Pt(L boolean AND L)] (L boolean AND L = acetyacetonate (acac) or 1,3-bis(2,4,6-trimethylphenyl)-propane-1,3-dionato (mesacac)) were synthesized and fully characterized. In addition, a Au(I) monocarbene complex was synthesized, isolated and characterized. Solid-state structures of two cyclometalated platinum(II) NOHC complexes and the Au(I) NOHC complex were obtained providing structural proof.
Synthesis and characterization of Pt(ii) and Au(i) complexes with N-oxy-heterocyclic carbene ligands (NOHCs) / Benin, A.; Kollar, J. I.; Riesebeck, T.; Wurl, F.; Graiff, C.; Strassner, T.; Tubaro, C.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - (2024). [10.1039/d4dt00996g]
Synthesis and characterization of Pt(ii) and Au(i) complexes with N-oxy-heterocyclic carbene ligands (NOHCs)
Graiff C.;
2024-01-01
Abstract
Two N-alkyloxy-N '-phenylimidazolium proligands and the corresponding platinum(II) cyclometalated N-alkyloxyimidazol-2-ylidene complexes with beta-diketonate auxiliary ligands, [(C-NOHC<^>C*)Pt(L boolean AND L)] (L boolean AND L = acetyacetonate (acac) or 1,3-bis(2,4,6-trimethylphenyl)-propane-1,3-dionato (mesacac)) were synthesized and fully characterized. In addition, a Au(I) monocarbene complex was synthesized, isolated and characterized. Solid-state structures of two cyclometalated platinum(II) NOHC complexes and the Au(I) NOHC complex were obtained providing structural proof.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
