Triptycene-based diiron(ii) and dizinc(ii) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(ii) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T(1/2 )at 243 K (Evans method).
Triptycene-based diiron(ii) mesocates: spin-crossover in solution / Mobili, R; Preda, G; Dondi, D; Monzani, E; Vadivel, D; Massera, C; Pasini, D; Amendola, V. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 60:42(2024), pp. 5522-5525. [10.1039/d4cc00812j]
Triptycene-based diiron(ii) mesocates: spin-crossover in solution
Massera, C;
2024-01-01
Abstract
Triptycene-based diiron(ii) and dizinc(ii) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(ii) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T(1/2 )at 243 K (Evans method).File in questo prodotto:
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