The synthetic relevance of [2.2.2]-bicyclooctadienes is witnessed by their successful application in various chemical domains, which prompted a recurrent interest towards the concise of these bridged bicycles. Seminal examples on the strategies to craft these compounds are presented, together with more recent applications that exploit visible light. In this context, a general intramolecular method for the para-cycloaddition of an allenamide arm onto simple aryl rings is highlighted.
A complementary route for alkene-arene para-cycloadditions via visiblelight- promoted triplet sensitization of allenamides / Maestri, G.; Serafino, A.. - In: SYNLETT. - ISSN 0936-5214. - (2023). [10.1055/a-2136-3947]
A complementary route for alkene-arene para-cycloadditions via visiblelight- promoted triplet sensitization of allenamides
Maestri G.
;Serafino A.
2023-01-01
Abstract
The synthetic relevance of [2.2.2]-bicyclooctadienes is witnessed by their successful application in various chemical domains, which prompted a recurrent interest towards the concise of these bridged bicycles. Seminal examples on the strategies to craft these compounds are presented, together with more recent applications that exploit visible light. In this context, a general intramolecular method for the para-cycloaddition of an allenamide arm onto simple aryl rings is highlighted.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
