A series of Zn-based Mixed-Ligand Metal-Organic-Frameworks (ML-MOFs) containing a bis-isonicotinoyl and a dicarboxylate linker have been solvothermally synthesized. The structural analyses evidence two types of framework entanglements, interpenetrated and polycatenated, that lead to materials featured by different porosity. The host-guest propensity of the materials toward different organic molecules is highlighted, with particular emphasis to the supramolecular organization adopted by the included guest molecules, as inferred by single-crystal X-ray diffraction analysis
Dynamic microporous mixed-ligand MOFs as adaptive crystalline containers for guest encapsulation and release* / Pelagatti, P.; Mazzeo, P. P.; Bacchi, A.; Giovanardi, D.. - (2023), pp. -64. (Intervento presentato al convegno Nanotechnology Materials and Devices Conference, NMDC 2023) [10.1109/NMDC57951.2023.10343768].
Dynamic microporous mixed-ligand MOFs as adaptive crystalline containers for guest encapsulation and release*
Pelagatti, P.
;Mazzeo, P. P.Membro del Collaboration Group
;Bacchi, A.Membro del Collaboration Group
;Giovanardi, D.Membro del Collaboration Group
2023-01-01
Abstract
A series of Zn-based Mixed-Ligand Metal-Organic-Frameworks (ML-MOFs) containing a bis-isonicotinoyl and a dicarboxylate linker have been solvothermally synthesized. The structural analyses evidence two types of framework entanglements, interpenetrated and polycatenated, that lead to materials featured by different porosity. The host-guest propensity of the materials toward different organic molecules is highlighted, with particular emphasis to the supramolecular organization adopted by the included guest molecules, as inferred by single-crystal X-ray diffraction analysisI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
