The merging of a homogeneous photocatalytic system with an electrochemical cell, having exchanged electrons as the only common point, has been recently demonstrated. This combination opens unexplored pathways in synthesis and allowed net-oxidative photocatalytic processes to be realized in the absence of a chemical oxidant, including: 1) the C−H alkylation of heteroarenes and 2) the coupling of azoles with arenes in the presence of an electrogenerated photocatalyst.
Merging Photocatalysis with Electrochemistry: The Dawn of a new Alliance in Organic Synthesis / Capaldo, Luca; LORENZO LAFAYETTE, Quadri; Ravelli, Davide. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 58:49(2019), pp. 17508-17510. [10.1002/anie.201910348]
Merging Photocatalysis with Electrochemistry: The Dawn of a new Alliance in Organic Synthesis
Luca Capaldo;Davide Ravelli
2019-01-01
Abstract
The merging of a homogeneous photocatalytic system with an electrochemical cell, having exchanged electrons as the only common point, has been recently demonstrated. This combination opens unexplored pathways in synthesis and allowed net-oxidative photocatalytic processes to be realized in the absence of a chemical oxidant, including: 1) the C−H alkylation of heteroarenes and 2) the coupling of azoles with arenes in the presence of an electrogenerated photocatalyst.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
