A photoelectrochemical strategy for the cross-dehydrogenative coupling of unactivated aliphatic hydrogen donors (e.g. alkanes) with benzothiazoles is reported. We used tetrabutylammonium decatungstate as the photocatalyst to activate strong C(sp3)–H bonds in the chosen substrates, while electrochemistry scavenged the extra electrons.
Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C–H bonds / Capaldo, L; Quadri, Ll; Merli, Daniele; Ravelli, D. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 57:(2021), pp. 4424-4427. [10.1039/d1cc01012c]
Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C–H bonds
Capaldo L;Ravelli D
2021-01-01
Abstract
A photoelectrochemical strategy for the cross-dehydrogenative coupling of unactivated aliphatic hydrogen donors (e.g. alkanes) with benzothiazoles is reported. We used tetrabutylammonium decatungstate as the photocatalyst to activate strong C(sp3)–H bonds in the chosen substrates, while electrochemistry scavenged the extra electrons.File in questo prodotto:
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