Solid [CuI(piperazine)0.5]∞, characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed.

Dual luminescence in solid Cui(piperazine): Hypothesis of an emissive 1-D delocalized excited state / Maini, L.; Braga, D.; Mazzeo, P. P.; Maschio, L.; Rerat, M.; Manet, I.; Ventura, B.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 44:29(2015), pp. 13003-13006. [10.1039/c5dt02204e]

Dual luminescence in solid Cui(piperazine): Hypothesis of an emissive 1-D delocalized excited state

Mazzeo P. P.;
2015-01-01

Abstract

Solid [CuI(piperazine)0.5]∞, characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed.
2015
Dual luminescence in solid Cui(piperazine): Hypothesis of an emissive 1-D delocalized excited state / Maini, L.; Braga, D.; Mazzeo, P. P.; Maschio, L.; Rerat, M.; Manet, I.; Ventura, B.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 44:29(2015), pp. 13003-13006. [10.1039/c5dt02204e]
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2940432
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 22
  • ???jsp.display-item.citation.isi??? 21
social impact