: Iron-catalysed C-H alkylations with alkenes were achieved on benzamides by N-triazole assistance. A notable switch of the regioselectivity from linear to branched was observed depending on the nature of the olefin employed. The approach allowed for the synthesis of a family of decorated benzamides with ample scope and high levels of chemo-, regio- and site-selectivity.
Triazole-enabled, iron-catalysed linear/branched selective C-H alkylations with alkenes / Cattani, Silvia; Secchi, Andrea; Ackermann, Lutz; Cera, Gianpiero. - In: ORGANIC & BIOMOLECULAR CHEMISTRY. - ISSN 1477-0520. - 21:6(2023), pp. 1264-1269. [10.1039/d2ob02206k]
Triazole-enabled, iron-catalysed linear/branched selective C-H alkylations with alkenes
Secchi, Andrea;Cera, Gianpiero
2023-01-01
Abstract
: Iron-catalysed C-H alkylations with alkenes were achieved on benzamides by N-triazole assistance. A notable switch of the regioselectivity from linear to branched was observed depending on the nature of the olefin employed. The approach allowed for the synthesis of a family of decorated benzamides with ample scope and high levels of chemo-, regio- and site-selectivity.File in questo prodotto:
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