Calixarenes represent a fascinating class of macrocycles with several applications in supramolecular chemistry such as synthetic receptors for ion recognition, prototypes of molecular machines and devices and catalysts. In this scenario, larger calix[6]-and calix[8]arenes represent a modular platform to build novel and more efficient organometallic catalysts. Within this digest review, we aim to survey the latest advancements in this area of research including CAC and C-Het bond formations and fundamental inor-ganic transformations such as ammonia production and carbon dioxide reduction. (c) 2022 Elsevier Ltd. All rights reserved.
Recent advances with calix[6]- and calix[8]arene organometallic catalysts / Bonati, Fc; Secchi, A; Cera, G. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 112:(2022), p. 154221. [10.1016/j.tetlet.2022.154221]
Recent advances with calix[6]- and calix[8]arene organometallic catalysts
Secchi, A
;Cera, G
2022-01-01
Abstract
Calixarenes represent a fascinating class of macrocycles with several applications in supramolecular chemistry such as synthetic receptors for ion recognition, prototypes of molecular machines and devices and catalysts. In this scenario, larger calix[6]-and calix[8]arenes represent a modular platform to build novel and more efficient organometallic catalysts. Within this digest review, we aim to survey the latest advancements in this area of research including CAC and C-Het bond formations and fundamental inor-ganic transformations such as ammonia production and carbon dioxide reduction. (c) 2022 Elsevier Ltd. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
