The crystal-structure analyses of the complexes [AlCl3(RNO2)] (R = Me or Ph) and NMR data in solution suggest a stronger Al-O co-ordinative interaction in the case of nitrobenzene compared to nitromethane; this could account for the dramatic solvent effects observed during certain electrophilic acylation processes involving AlCl3 as a promoter.
Dalton communications. Organic nitro compounds as ligands. A comparison between the ligand behaviour of MeNO2 and PhNO2 towards AlCl3 / Lanfranchi, M.; Pellinghelli, M. A.; Predieri, G.; Bigi, F.; Maggi, R.; Sartori, G.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - 9(1993), pp. 1463-1464. [10.1039/DT9930001463]
Dalton communications. Organic nitro compounds as ligands. A comparison between the ligand behaviour of MeNO2 and PhNO2 towards AlCl3
Lanfranchi M.;Pellinghelli M. A.;Predieri G.;Bigi F.;Maggi R.;Sartori G.
1993-01-01
Abstract
The crystal-structure analyses of the complexes [AlCl3(RNO2)] (R = Me or Ph) and NMR data in solution suggest a stronger Al-O co-ordinative interaction in the case of nitrobenzene compared to nitromethane; this could account for the dramatic solvent effects observed during certain electrophilic acylation processes involving AlCl3 as a promoter.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
