2,6-Diacetylpyridine bis(benzoylhydrazone) (H2DPBH) is proposed as a ligand for the extraction of uranium(VI). Complete extraction from aqueous solutions into dichloromethane is achieved with a ligand/metal mole ratio of < for 10-5-10-4 M uranyl ion. Potentiometric measurements indicate that the extracted species is UO2 (DPBH). Uranium can be determined in the extract by spectrophotometric measurements at 420 nm and by differentail pulse polarography (Ep = -0.67 V) with tetraethylammonium bromide as supporting electrolyte. For both methods, the detection limit is about 2 × 10-6 M in the extract. © 1986.
Liquid-liquid extraction and determination of uranium(IV) with 2,6-diacetylpyridine bis(benzoylhydrazone) / Casoli, A.; Mangia, A.; Mori, G.; Predieri, G.. - In: ANALYTICA CHIMICA ACTA. - ISSN 0003-2670. - 186:C(1986), pp. 283-287. [10.1016/S0003-2670(00)81798-5]
Liquid-liquid extraction and determination of uranium(IV) with 2,6-diacetylpyridine bis(benzoylhydrazone)
Casoli A.
;Predieri G.
1986-01-01
Abstract
2,6-Diacetylpyridine bis(benzoylhydrazone) (H2DPBH) is proposed as a ligand for the extraction of uranium(VI). Complete extraction from aqueous solutions into dichloromethane is achieved with a ligand/metal mole ratio of < for 10-5-10-4 M uranyl ion. Potentiometric measurements indicate that the extracted species is UO2 (DPBH). Uranium can be determined in the extract by spectrophotometric measurements at 420 nm and by differentail pulse polarography (Ep = -0.67 V) with tetraethylammonium bromide as supporting electrolyte. For both methods, the detection limit is about 2 × 10-6 M in the extract. © 1986.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
