We present a simple way of estimating the entropy cost of solvate formation in crystals. The entropy penalty of making solvates can be as low as <1 kJ mol−1 or as high as >9 kJ mol−1 and is entirely dependent on the nature of the liquid component and the temperature of solvate formation. A link is found between a low entropy cost and a higher likelihood for a solvent to make solvates.
On the entropy cost of making solvates / Cruz-Cabeza, Aurora J.; Wright, Sarah E.; Bacchi, Alessia. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 56:38(2020), pp. 5127-5130. [10.1039/D0CC01050B]
On the entropy cost of making solvates
Bacchi, Alessia
2020-01-01
Abstract
We present a simple way of estimating the entropy cost of solvate formation in crystals. The entropy penalty of making solvates can be as low as <1 kJ mol−1 or as high as >9 kJ mol−1 and is entirely dependent on the nature of the liquid component and the temperature of solvate formation. A link is found between a low entropy cost and a higher likelihood for a solvent to make solvates.File in questo prodotto:
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