The Catellani reaction is a multi-component cascade sequence, catalysed by palladium and norbornene, which typically uses aromatic starting materials. Now, through the use of a modified norbornene co-catalyst, the scope of this reaction has been extended to alkenyl reagents, enabling the preparation of all-carbon tetrasubstituted olefins
Alkenyl boost for Catellani / Maestri, Giovanni; Derat, Etienne. - In: NATURE CHEMISTRY. - ISSN 1755-4330. - 11:12(2019), pp. 1082-1084. [10.1038/s41557-019-0361-3]
Alkenyl boost for Catellani
Maestri, Giovanni
;
2019-01-01
Abstract
The Catellani reaction is a multi-component cascade sequence, catalysed by palladium and norbornene, which typically uses aromatic starting materials. Now, through the use of a modified norbornene co-catalyst, the scope of this reaction has been extended to alkenyl reagents, enabling the preparation of all-carbon tetrasubstituted olefinsFile in questo prodotto:
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