Investigations into the distal-functionalisation of the phenols of racemic C-4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography.[GRAPHICS].

Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes / Tan, D. A.; Massera, C.; Mocerino, M.. - In: SUPRAMOLECULAR CHEMISTRY. - ISSN 1061-0278. - 31:7(2019), pp. 442-450. [10.1080/10610278.2019.1620949]

Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes

Massera C.;MOCERINO, MAURIZIO
2019

Abstract

Investigations into the distal-functionalisation of the phenols of racemic C-4-symmetric tetramethoxyresorcinarene has led to a simple, single-step procedure that allows the isolation of gram quantities of partially silylated derivatives, with the targeted distally silylated resorcinarene being obtained in a yield of 31%. These partially silylated derivatives would serve as versatile intermediates for the selective functionalisation of this elegant architecture. The solid-state structures of many of these derivatives have been determined by single crystal X-ray crystallography.[GRAPHICS].
Partial functionalisation of C4-symmetric tetramethoxyresorcinarenes / Tan, D. A.; Massera, C.; Mocerino, M.. - In: SUPRAMOLECULAR CHEMISTRY. - ISSN 1061-0278. - 31:7(2019), pp. 442-450. [10.1080/10610278.2019.1620949]
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11381/2865990
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