Magnetite nanoparticles are prepared by non-hydrolytic sol-gel process in the presence of iron(III)-acetylacetonate as precursor and 2-ethyl-1,3-hexanediol as reactive solvent; the nanoparticle size is affected by the precursor-to-solvent ratio. The suspensions, mixed with bisphenol-A diglycidyl ether, are cured in the presence of ytterbium(III) trifluoromethanesulfonate as cationic initiator. The chain-growth polymerization results in a three-dimensional network where the diol, acting at the same time as reactive solvent and suspending medium, is covalently linked to the epoxy network according to the “activated monomer” mechanism. The filler induces stiffening because of hydrodynamic effects and of a better cross-linking ability in the nanocomposite. Magnetite nanoparticles form aggregates whose size and shape depend on concentration. Isothermal magnetization loops and FC/ZFC DC susceptibility curves indicate that all nanocomposites are dominated by interparticle magnetic interactions resulting in a collective response whose details depend on nanoparticle concentration and degree of aggregation.

Magnetite-epoxy nanocomposites obtained by the reactive suspension method: Microstructural, thermo-mechanical and magnetic properties / Barrera, G.; Sciancalepore, C.; Messori, M.; Allia, P.; Tiberto, P.; Bondioli, F.. - In: EUROPEAN POLYMER JOURNAL. - ISSN 0014-3057. - 94:(2017), pp. 354-365. [10.1016/j.eurpolymj.2017.07.022]

Magnetite-epoxy nanocomposites obtained by the reactive suspension method: Microstructural, thermo-mechanical and magnetic properties

Sciancalepore, C.
Investigation
;
Bondioli, F.
Writing – Review & Editing
2017-01-01

Abstract

Magnetite nanoparticles are prepared by non-hydrolytic sol-gel process in the presence of iron(III)-acetylacetonate as precursor and 2-ethyl-1,3-hexanediol as reactive solvent; the nanoparticle size is affected by the precursor-to-solvent ratio. The suspensions, mixed with bisphenol-A diglycidyl ether, are cured in the presence of ytterbium(III) trifluoromethanesulfonate as cationic initiator. The chain-growth polymerization results in a three-dimensional network where the diol, acting at the same time as reactive solvent and suspending medium, is covalently linked to the epoxy network according to the “activated monomer” mechanism. The filler induces stiffening because of hydrodynamic effects and of a better cross-linking ability in the nanocomposite. Magnetite nanoparticles form aggregates whose size and shape depend on concentration. Isothermal magnetization loops and FC/ZFC DC susceptibility curves indicate that all nanocomposites are dominated by interparticle magnetic interactions resulting in a collective response whose details depend on nanoparticle concentration and degree of aggregation.
2017
Magnetite-epoxy nanocomposites obtained by the reactive suspension method: Microstructural, thermo-mechanical and magnetic properties / Barrera, G.; Sciancalepore, C.; Messori, M.; Allia, P.; Tiberto, P.; Bondioli, F.. - In: EUROPEAN POLYMER JOURNAL. - ISSN 0014-3057. - 94:(2017), pp. 354-365. [10.1016/j.eurpolymj.2017.07.022]
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2836654
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 15
  • ???jsp.display-item.citation.isi??? 14
social impact