Two py-functionalized perylene-bis-imide ligands were synthesized and used to make bimetallic half-sandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy and elemental analysis. The complexes are wheel-and-axle compounds where the axle is the divergent ligand and the wheels are the [(p-cymene)RuCl2] units. The complexes, but not the free ligands, showed absorption of VOCs such as toluene and xylenes through heterogeneous solid-gas uptakes. The reactivity is ascribable to the waa geometry, likely by an upset of the high stacking characterizing the crystalline frameworks of the free ligands. The kinetic profiles of the uptake reactions were determined.

SORPTION PROPERTIES TOWARDS ENVIRONMENTALLY IMPORTANT VOCs of HALF-SANDWICH Ru(II) COMPLEXES CONTAINING PERYLENE-BIS-IMIDE LIGANDS / Paolo, Pagano; Pelagatti, Paolo; Bacchi, Alessia; Michele R., Chierotti; Susan A., Bourne; Gift, Mehlana. - In: INORGANIC AND NANO-METAL CHEMISTRY. - ISSN 2470-1556. - 47:3(2017), pp. 427-432. [10.1080/15533174.2016.1186068]

SORPTION PROPERTIES TOWARDS ENVIRONMENTALLY IMPORTANT VOCs of HALF-SANDWICH Ru(II) COMPLEXES CONTAINING PERYLENE-BIS-IMIDE LIGANDS

PELAGATTI, Paolo
Supervision
;
BACCHI, Alessia
Membro del Collaboration Group
;
2017

Abstract

Two py-functionalized perylene-bis-imide ligands were synthesized and used to make bimetallic half-sandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy and elemental analysis. The complexes are wheel-and-axle compounds where the axle is the divergent ligand and the wheels are the [(p-cymene)RuCl2] units. The complexes, but not the free ligands, showed absorption of VOCs such as toluene and xylenes through heterogeneous solid-gas uptakes. The reactivity is ascribable to the waa geometry, likely by an upset of the high stacking characterizing the crystalline frameworks of the free ligands. The kinetic profiles of the uptake reactions were determined.
SORPTION PROPERTIES TOWARDS ENVIRONMENTALLY IMPORTANT VOCs of HALF-SANDWICH Ru(II) COMPLEXES CONTAINING PERYLENE-BIS-IMIDE LIGANDS / Paolo, Pagano; Pelagatti, Paolo; Bacchi, Alessia; Michele R., Chierotti; Susan A., Bourne; Gift, Mehlana. - In: INORGANIC AND NANO-METAL CHEMISTRY. - ISSN 2470-1556. - 47:3(2017), pp. 427-432. [10.1080/15533174.2016.1186068]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2827570
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