We present here a reaction scheme to connect TbPc2 single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc2, we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme.
Formation of TbPc2 Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis / Pedrini, Alessandro; Perfetti, Mauro; Mannini, Matteo; Dalcanale, Enrico. - In: ACS OMEGA. - ISSN 2470-1343. - 2:2(2017), pp. 517-521. [10.1021/acsomega.6b00546]
Formation of TbPc2 Single-Molecule Magnets’ Covalent 1D Structures via Acyclic Diene Metathesis
PEDRINI, Alessandro;DALCANALE, Enrico
2017-01-01
Abstract
We present here a reaction scheme to connect TbPc2 single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc2, we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
