Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.

Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems­: Valuable Vinylogous Donor Substrates in Synthesis / Battistini, Lucia; Curti, Claudio; Rassu, Gloria; Sartori, Andrea; Zanardi, Franca. - In: SYNTHESIS. - ISSN 0039-7881. - 49(2017), pp. 2297-2336. [10.1055/s-0036-1589487]

Enolizable Alkylidene Heterocyclic and Carbocyclic Carbonyl Systems­: Valuable Vinylogous Donor Substrates in Synthesis

BATTISTINI, Lucia;CURTI, Claudio;SARTORI, Andrea;ZANARDI, Franca
2017

Abstract

Controlled vinylogous carbon–carbon bond-forming reactions are useful options for providing the selective remote functionalization of conjugated carbonyl substrates. Remotely enolizable alkylidene heterocyclic and carbocyclic carbonyl compounds are pro-nucleophilic substrates that may be engaged in highly valuable chemical transformations. This review emphasizes the merits of these recently discovered vinylogous donors in the chemo-, regio- and stereoselective synthesis of many functionality-rich products.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11381/2823318
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