The reactions of diphenylamine and benzoyl isothiocyanates with phenacyl bromide or methyl 2-bromoacetate in the presence of triethylamine yield 2,4,5-trisubstituted thiazole derivatives. The molecular structures of [2-(diphenylamino)-4-phenylthiazol-5-yl](o-tolyl) methanone and methyl 4-(4-chlorophenyl)-2-(diphenylamino)thiazole-5-carboxylate have been fully determined by means of single crystal X-ray diffraction methods.
Synthesis and crystal structures of some new 2-(diphenylamino)-4,5-disubstituted thiazole derivatives / Heydari, Reza; Shahrekipour, Fahimeh; Graiff, Claudia; Tahamipour, Batool. - In: JOURNAL OF CHEMICAL RESEARCH. - ISSN 1747-5198. - 40:6(2016), pp. 326-330. [10.3184/174751916X14610676453088]
Synthesis and crystal structures of some new 2-(diphenylamino)-4,5-disubstituted thiazole derivatives
GRAIFF, Claudia;
2016-01-01
Abstract
The reactions of diphenylamine and benzoyl isothiocyanates with phenacyl bromide or methyl 2-bromoacetate in the presence of triethylamine yield 2,4,5-trisubstituted thiazole derivatives. The molecular structures of [2-(diphenylamino)-4-phenylthiazol-5-yl](o-tolyl) methanone and methyl 4-(4-chlorophenyl)-2-(diphenylamino)thiazole-5-carboxylate have been fully determined by means of single crystal X-ray diffraction methods.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
