A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.
Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives / Stojkovic, Danijela; Bacchi, Alessia; Capucci, Davide; Milenkovic, Milica; Cobeljic, Bozidar; Trifunovic, Srecko; Andjelkovic, Katarina; Jevtic, Verica; Vukovic, Nenad; Vukic, Milena; Sladic, Dusan. - In: JOURNAL OF THE SERBIAN CHEMICAL SOCIETY. - ISSN 0352-5139. - 81:12(2016), pp. 1383-1392. [10.2298/JSC160915087S]
Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives
BACCHI, Alessia;CAPUCCI, Davide;
2016-01-01
Abstract
A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
