A 12-metallacrown-4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture. The connection of the four-fold symmetric MC subunits by CuII nodes led to the formation of 2D layers of metallacrowns. Channels are present in the crystalline architecture, which exhibits permanent porosity manifested in N2 and CO2 uptake capacity.
Design of 2D Porous Coordination Polymers Based on Metallacrown Units / Atzeri, Corrado; Marchio', Luciano; Chow, Chun Y.; Kampf, Jeff W.; Pecoraro, Vincent L; Tegoni, Matteo. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 22:19(2016), pp. 6482-6486. [10.1002/chem.201600562]
Design of 2D Porous Coordination Polymers Based on Metallacrown Units
ATZERI, Corrado;MARCHIO', Luciano;TEGONI, Matteo
2016-01-01
Abstract
A 12-metallacrown-4 (MC) complex was designed and employed as the building block in the synthesis of coordination polymers, one of which is the first permanently porous MC architecture. The connection of the four-fold symmetric MC subunits by CuII nodes led to the formation of 2D layers of metallacrowns. Channels are present in the crystalline architecture, which exhibits permanent porosity manifested in N2 and CO2 uptake capacity.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
