Highly sym. [Pd3]+ clusters that present delocalized metal-metal bonds can catalyze the selective semi-redn. of internal alkynes to cis-alkenes. Studies on factors governing the formation of all-metal aroms. enabled the design of an optimized catalytic system that delivers cis-alkenes with almost complete selectivity on a gram scale with very low catalyst loadings (0.03 mol%)
Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes / Monfredini, Anna; Santacroce, Veronica; Deyris, Pierre Alexandre; Maggi, Raimondo; Bigi, Franca; Maestri, Giovanni; Malacria, Max. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 45:(2016), pp. 15786-15790. [10.1039/C6DT01840H]
Boosting Catalyst Activity in Cis-Selective Semi-Reduction of Internal Alkynes by Tailoring the Assembly of All-Metal Aromatic Tri-Palladium Complexes
MONFREDINI, ANNA;SANTACROCE, Veronica;MAGGI, Raimondo;BIGI, Franca;MAESTRI, Giovanni;
2016-01-01
Abstract
Highly sym. [Pd3]+ clusters that present delocalized metal-metal bonds can catalyze the selective semi-redn. of internal alkynes to cis-alkenes. Studies on factors governing the formation of all-metal aroms. enabled the design of an optimized catalytic system that delivers cis-alkenes with almost complete selectivity on a gram scale with very low catalyst loadings (0.03 mol%)| File | Dimensione | Formato | |
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