A simple catalytic method involving all-metal aromatic frameworks as precatalysts ensures an efficient route to (Z)-alkenes. Aromatic triangular palladium clusters were used to reduce internal alkynes without any trace of the formation of alkane side products. These trinuclear complexes provide a catalytic system that parallels the activity and selectivity of their best mononuclear peers, and the catalyst likely operates through complementary mechanisms
Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes / Deyris, Pierre Alexandre; Cañeque, Tatiana; Wang, Yanlan; Retailleau, Pascal; Bigi, Franca; Maggi, Raimondo; Maestri, Giovanni; Malacria, Max. - In: CHEMCATCHEM. - ISSN 1867-3899. - 7:20(2015), pp. 3266-3269. [10.1002/cctc.201500729]
Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes
BIGI, Franca;MAGGI, Raimondo;MAESTRI, Giovanni;
2015-01-01
Abstract
A simple catalytic method involving all-metal aromatic frameworks as precatalysts ensures an efficient route to (Z)-alkenes. Aromatic triangular palladium clusters were used to reduce internal alkynes without any trace of the formation of alkane side products. These trinuclear complexes provide a catalytic system that parallels the activity and selectivity of their best mononuclear peers, and the catalyst likely operates through complementary mechanismsI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
