A simple synthetic method allows the one-pot assembly of C3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics / Wang, Yanlan; Deyris, Pierre Alexandre; Caneque, Tatiana; Blanchard, Florent; Li, Yanling; Bigi, Franca; Maggi, Raimondo; Blanchard, Sebastien; Maestri, Giovanni; Malacria, Max. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 21:35(2015), pp. 12271-12274. [10.1002/chem.201501239]

A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics

BIGI, Franca;MAGGI, Raimondo;MAESTRI, Giovanni;
2015

Abstract

A simple synthetic method allows the one-pot assembly of C3-symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first examples of stable triangular all-metal heteroaromatics. In contrast to traditional heteroaromatic molecules formed combining main-group elements, they actually retain structural and electronic features of their homonuclear analogues
A Simple Synthesis of Triangular All-Metal Aromatics Allowing Access to Isolobal All-Metal Heteroaromatics / Wang, Yanlan; Deyris, Pierre Alexandre; Caneque, Tatiana; Blanchard, Florent; Li, Yanling; Bigi, Franca; Maggi, Raimondo; Blanchard, Sebastien; Maestri, Giovanni; Malacria, Max. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - 21:35(2015), pp. 12271-12274. [10.1002/chem.201501239]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2795032
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