A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,​6'-​(1E,​1'E)​-​(2-​hydroxypropane-​1,​3-​diyl)​bis(azan-​1-​yl-​1-​ylidene)​bis(methan-​1-​yl-​1-​ylidene)​bis(2-​methoxyphenol)​) with Cu(II) acetate and NaClO4. In addn. to the presence of alc. O-​Na coordination bonds, the single crystal x-​ray structure reveals that the 1-​dimensional coordination polymer is stabilized by the formation of phenyl-​Na η2-​bonds, face-​to-​face π-​π contacts and Cu-​π interactions.

A mixed valent heterometallic CuII​/NaI coordination polymer with sodium-​phenyl bonds / Amitabha, Datta; Kuheli, Das; Massera, Chiara; Jack K., Clegg; Chittaranjan, Sinha; Jui Hsien, Huang; Eugenio, Garribba. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 43:14(2014), pp. 5558-5563. [10.1039/c4dt00189c]

A mixed valent heterometallic CuII​/NaI coordination polymer with sodium-​phenyl bonds

MASSERA, Chiara;
2014-01-01

Abstract

A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,​6'-​(1E,​1'E)​-​(2-​hydroxypropane-​1,​3-​diyl)​bis(azan-​1-​yl-​1-​ylidene)​bis(methan-​1-​yl-​1-​ylidene)​bis(2-​methoxyphenol)​) with Cu(II) acetate and NaClO4. In addn. to the presence of alc. O-​Na coordination bonds, the single crystal x-​ray structure reveals that the 1-​dimensional coordination polymer is stabilized by the formation of phenyl-​Na η2-​bonds, face-​to-​face π-​π contacts and Cu-​π interactions.
2014
A mixed valent heterometallic CuII​/NaI coordination polymer with sodium-​phenyl bonds / Amitabha, Datta; Kuheli, Das; Massera, Chiara; Jack K., Clegg; Chittaranjan, Sinha; Jui Hsien, Huang; Eugenio, Garribba. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 43:14(2014), pp. 5558-5563. [10.1039/c4dt00189c]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2714495
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