This Tutorial Review summarizes recent examples of electrophilic activation of allenes with particular focus on analogies and differences between Lewis and Brønsted acid activation of these versatile substrates. The aim of this article is to present a general overview of the possibilities offered to chemists using complementary modes of catalysis and to emphasize advantages and limitations of each approach, thereby providing a means to expand the scope of this powerful synthetic methodology.

Electrophilic activation of allenenes and allenynes: analogies and differences between Brønsted and Lewis acid activation / T., Cañeque; F. M., Truscott; R., Rodriguez; Maestri, Giovanni; M., Malacria. - In: CHEMICAL SOCIETY REVIEWS. - ISSN 0306-0012. - 43:(2014), pp. 2916-2926. [10.1039/C4CS00023D]

Electrophilic activation of allenenes and allenynes: analogies and differences between Brønsted and Lewis acid activation

MAESTRI, Giovanni;
2014-01-01

Abstract

This Tutorial Review summarizes recent examples of electrophilic activation of allenes with particular focus on analogies and differences between Lewis and Brønsted acid activation of these versatile substrates. The aim of this article is to present a general overview of the possibilities offered to chemists using complementary modes of catalysis and to emphasize advantages and limitations of each approach, thereby providing a means to expand the scope of this powerful synthetic methodology.
2014
Electrophilic activation of allenenes and allenynes: analogies and differences between Brønsted and Lewis acid activation / T., Cañeque; F. M., Truscott; R., Rodriguez; Maestri, Giovanni; M., Malacria. - In: CHEMICAL SOCIETY REVIEWS. - ISSN 0306-0012. - 43:(2014), pp. 2916-2926. [10.1039/C4CS00023D]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2704494
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