The first C-3-symmetric 44-core-valence-electron triangular palladium clusters, [{(SAr)(PAr3)Pd}(3)](+), have been synthesized by activation of the CS bond of isothioureas. Owing to delocalized metal-metal bonding, these stable complexes are the first noble-metal analogues of the -aromatic cyclopropenyl cation [C3H3](+), with their all-metal aromaticity involving d-type atomic orbitals

Synthesis of Triangular Tripalladium Cations as Noble-Metal Analogues of the Cyclopropenyl Cation / S., Blanchard; L., Fensterbank; G., Gontard; E., Lacote; Maestri, Giovanni; M., Malacria. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 53:(2014), pp. 1987-1991. [10.1002/anie.201310204]

Synthesis of Triangular Tripalladium Cations as Noble-Metal Analogues of the Cyclopropenyl Cation

MAESTRI, Giovanni;
2014-01-01

Abstract

The first C-3-symmetric 44-core-valence-electron triangular palladium clusters, [{(SAr)(PAr3)Pd}(3)](+), have been synthesized by activation of the CS bond of isothioureas. Owing to delocalized metal-metal bonding, these stable complexes are the first noble-metal analogues of the -aromatic cyclopropenyl cation [C3H3](+), with their all-metal aromaticity involving d-type atomic orbitals
2014
Synthesis of Triangular Tripalladium Cations as Noble-Metal Analogues of the Cyclopropenyl Cation / S., Blanchard; L., Fensterbank; G., Gontard; E., Lacote; Maestri, Giovanni; M., Malacria. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 53:(2014), pp. 1987-1991. [10.1002/anie.201310204]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2691900
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