A method for the synthesis of phenanthridines from benzylamines and aryl iodides which uses a dual palladium-catalyzed process is developed. The domino sequence ends via an intramolecular amination and an oxidative dehydrogenation. No protecting group or prefunctionalization of the amine is required, and the process uses dioxygen as the terminal oxidant
Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis / Maestri, Giovanni; M., Larraufie; E., Derat; C., Ollivier; L., Fensterbank; E., Lacote; M., Malacria. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 12:(2010), pp. 5692-5695. [10.1021/ol102509n]
Expeditious Synthesis of Phenanthridines from Benzylamines via Dual Palladium Catalysis
MAESTRI, Giovanni;
2010-01-01
Abstract
A method for the synthesis of phenanthridines from benzylamines and aryl iodides which uses a dual palladium-catalyzed process is developed. The domino sequence ends via an intramolecular amination and an oxidative dehydrogenation. No protecting group or prefunctionalization of the amine is required, and the process uses dioxygen as the terminal oxidantFile in questo prodotto:
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