A six-membered N,C-palladacycle bearing the 2-phenylaniline bidentate ligand (1) and three other palladium complexes of a phosphorus ylide (2, 3 and 4) were utilized in Suzuki reactions between phenylboronic acid and a number of aryl bromides and chlorides. The complexes were found to be capable homogeneous catalysts for a variety of substrates, affording the coupled products in good to excellent yields. The structure of compound I, determined by X-ray diffraction, is also reported.

Catalytic activity of some palladium complexes of a phosphorus ylide and structure of a 2-phenylaniline-based palladacycle complex / N., Rahimi; K., Karami; Rizzoli, Corrado. - In: POLYHEDRON. - ISSN 0277-5387. - 59:(2013), pp. 133-137. [10.1016/j.poly.2013.04.055]

Catalytic activity of some palladium complexes of a phosphorus ylide and structure of a 2-phenylaniline-based palladacycle complex

RIZZOLI, Corrado
2013-01-01

Abstract

A six-membered N,C-palladacycle bearing the 2-phenylaniline bidentate ligand (1) and three other palladium complexes of a phosphorus ylide (2, 3 and 4) were utilized in Suzuki reactions between phenylboronic acid and a number of aryl bromides and chlorides. The complexes were found to be capable homogeneous catalysts for a variety of substrates, affording the coupled products in good to excellent yields. The structure of compound I, determined by X-ray diffraction, is also reported.
2013
Catalytic activity of some palladium complexes of a phosphorus ylide and structure of a 2-phenylaniline-based palladacycle complex / N., Rahimi; K., Karami; Rizzoli, Corrado. - In: POLYHEDRON. - ISSN 0277-5387. - 59:(2013), pp. 133-137. [10.1016/j.poly.2013.04.055]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2644868
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