A mixed valent copper complex [CuIICuI(L)(μ-SCN)(μ3-SCN)]n (LH = N′-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent CuII–CuI interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial CuII → CuI reduction is observed in this system at room temperature.
A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains / D. Sadhukhan; C. Rizzoli; E. Garribba; C. J. Gomez Garcia; A. Yahia-Ammar; L. Charbonniere; S. Mitra. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 41(2012), pp. 11565-11568.
Tipologia ministeriale: | Articolo su rivista |
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