A mixed valent copper complex [CuIICuI(L)(μ-SCN)(μ3-SCN)]n (LH = N′-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent CuII–CuI interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial CuII → CuI reduction is observed in this system at room temperature.
A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains / D., Sadhukhan; Rizzoli, Corrado; E., Garribba; C. J., Gomez Garcia; A., Yahia Ammar; L., Charbonniere; S., Mitra. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 41:(2012), pp. 11565-11568. [10.1039/C2DT31666H]
A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains
RIZZOLI, Corrado;
2012-01-01
Abstract
A mixed valent copper complex [CuIICuI(L)(μ-SCN)(μ3-SCN)]n (LH = N′-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent CuII–CuI interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial CuII → CuI reduction is observed in this system at room temperature.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
