A mixed valent copper complex [CuIICuI(L)(μ-SCN)(μ3-SCN)]n (LH = N′-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent CuII–CuI interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial CuII → CuI reduction is observed in this system at room temperature.

A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains / D., Sadhukhan; Rizzoli, Corrado; E., Garribba; C. J., Gomez Garcia; A., Yahia Ammar; L., Charbonniere; S., Mitra. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 41:(2012), pp. 11565-11568. [10.1039/C2DT31666H]

A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains

RIZZOLI, Corrado;
2012-01-01

Abstract

A mixed valent copper complex [CuIICuI(L)(μ-SCN)(μ3-SCN)]n (LH = N′-((pyridin-2-yl)methylene)acetohydrazide) has been synthesized and characterized. It is a unique example of a 2D mixed valent CuII–CuI interlinked molecular assembly with a very unusual bridging property of the hydrazone ligand. An extraordinary in situ partial CuII → CuI reduction is observed in this system at room temperature.
2012
A Novel Mixed Valent CuII-CuI 2D Framework Made of a Hydrazone and µ-SCN Bridged Metallacyclic Loops Cross-linked by µ3-SCN Chains / D., Sadhukhan; Rizzoli, Corrado; E., Garribba; C. J., Gomez Garcia; A., Yahia Ammar; L., Charbonniere; S., Mitra. - In: DALTON TRANSACTIONS. - ISSN 1477-9234. - 41:(2012), pp. 11565-11568. [10.1039/C2DT31666H]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2456635
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