A novel polymeric complex has been synthesized by refluxing disodium acetylene dicarboxylate with tributyltin chloride in dry methanol. The solid state structure of the complex has been determined by single crystal X-ray analysis. The tin(IV) metal exhibits distorted trigonal bipyramidal geometry. Each carboxylate group of the ligand acts in a bidentate fashion linking adjacent metal atoms to produce polymeric chains which are cross linked into a three-dimensional network.
Polymeric three dimensional crystal structure of a tributyltin(IV) derivative with acetylene dicarboxylic acid / S., Hussain; S., Ali; S., Shahzadi; Rizzoli, Corrado. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - 188:6(2013), pp. 812-818. [10.1080/10426507.2012.710675]
Polymeric three dimensional crystal structure of a tributyltin(IV) derivative with acetylene dicarboxylic acid
RIZZOLI, Corrado
2013-01-01
Abstract
A novel polymeric complex has been synthesized by refluxing disodium acetylene dicarboxylate with tributyltin chloride in dry methanol. The solid state structure of the complex has been determined by single crystal X-ray analysis. The tin(IV) metal exhibits distorted trigonal bipyramidal geometry. Each carboxylate group of the ligand acts in a bidentate fashion linking adjacent metal atoms to produce polymeric chains which are cross linked into a three-dimensional network.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
