The chromatographic behaviour of some monosubstituted derivatives of the tetranuclear cluster (Cp)NiOs3 (μH)3(CO)9 (Cp = cyclopentadienyl) with groupVdonorligands (benzonitrile tertiary phosphines, triphenylamine and triphenylstibine) is reported. In reversed-phase and adsorption liquid chromatography, the kind of the substituents strongly influences the retention volumes, the dimension of the whole cluster having less effect. Correlations of retention volumes with the nature of the substituents were found only for small of compounds

Behaviour of tetrahedral nickel-triosmium carbonyl cluster and its monosubstitued derivatives with group V donor ligands in high-performance liquid cromatography / Casoli, Antonella; Mangia, Alessandro; Predieri, Giovanni. - In: ANALYTICA CHIMICA ACTA. - ISSN 0003-2670. - 176:(1985), pp. 259-262. [10.1016/S0003-2670(00)81652-9]

Behaviour of tetrahedral nickel-triosmium carbonyl cluster and its monosubstitued derivatives with group V donor ligands in high-performance liquid cromatography

CASOLI, Antonella;MANGIA, Alessandro;PREDIERI, Giovanni
1985-01-01

Abstract

The chromatographic behaviour of some monosubstituted derivatives of the tetranuclear cluster (Cp)NiOs3 (μH)3(CO)9 (Cp = cyclopentadienyl) with groupVdonorligands (benzonitrile tertiary phosphines, triphenylamine and triphenylstibine) is reported. In reversed-phase and adsorption liquid chromatography, the kind of the substituents strongly influences the retention volumes, the dimension of the whole cluster having less effect. Correlations of retention volumes with the nature of the substituents were found only for small of compounds
Behaviour of tetrahedral nickel-triosmium carbonyl cluster and its monosubstitued derivatives with group V donor ligands in high-performance liquid cromatography / Casoli, Antonella; Mangia, Alessandro; Predieri, Giovanni. - In: ANALYTICA CHIMICA ACTA. - ISSN 0003-2670. - 176:(1985), pp. 259-262. [10.1016/S0003-2670(00)81652-9]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11381/2440866
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