The calorimetric response was analyzed both for elec. and chem. input and Tian's equation parameters were evaluated, when applied to flow microcalorimetry. It is possible to calc. the power emitted by a given process, in a steady-state expt., independently from the elec. calibration, taking into account the residual heat flowing out with the liq. Application to the protonation enthalpies of D-cycloserine is shown.
Continuous gradient method in flow microcalorimetry. Part I. Relation between electrical and chemical calibration / Fisicaro, Emilia. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - 113:(1987), pp. 125-131. [10.1016/0040-6031(87)]
Continuous gradient method in flow microcalorimetry. Part I. Relation between electrical and chemical calibration
FISICARO, Emilia
1987-01-01
Abstract
The calorimetric response was analyzed both for elec. and chem. input and Tian's equation parameters were evaluated, when applied to flow microcalorimetry. It is possible to calc. the power emitted by a given process, in a steady-state expt., independently from the elec. calibration, taking into account the residual heat flowing out with the liq. Application to the protonation enthalpies of D-cycloserine is shown.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.