The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine-ketone fragment is approximately planar [maximum deviation = 0.026 (3) angstrom] and forms a dihedral angle of 39.78 (3)degrees with the naphthalene ring system. An intramolecular N-H center dot center dot center dot O hydrogen bond is observed.
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