The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine-ketone fragment is approximately planar [maximum deviation = 0.026 (3) angstrom] and forms a dihedral angle of 39.78 (3)degrees with the naphthalene ring system. An intramolecular N-H center dot center dot center dot O hydrogen bond is observed.
Z-4-(2-Naphthylamino)pent-3-en-2-one / M. A., Harrad; B., Boualy; A., Oudahmane; D., Avignant; Rizzoli, Corrado. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - E67:(2011), pp. o1818-o1818. [10.1107/S1600536811024494]
Z-4-(2-Naphthylamino)pent-3-en-2-one
RIZZOLI, Corrado
2011-01-01
Abstract
The title compound, C15H15NO, which was synthesized under solvent-free conditions by the reaction of acetoacetone and 2-naphthylamine, adopts a Z conformation about the C=C bond. The enamine-ketone fragment is approximately planar [maximum deviation = 0.026 (3) angstrom] and forms a dihedral angle of 39.78 (3)degrees with the naphthalene ring system. An intramolecular N-H center dot center dot center dot O hydrogen bond is observed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
