The title compound, C16H19NO, was synthesized under solvent-free conditions by reaction of 7-oxa-bicyclo[4.1.0]-heptane and naphthalen-1-amine in the presence of Ca(CF3COO)(2) as catalyst. The cyclohexane ring adopts a chair conformation. In the crystal, molecules are linked by intermolecular N-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi interactions into chains parallel to the c axis.
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