In the cation of the title compound, [Pd(C26H19NO3P)(C26H24P2)]CF3O3S center dot CH2Cl2 center dot 0.5C(6)H(14), the PdII atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC3P and PdC2P2 five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, intermolecular C-H...O hydrogen bonds link cations and anions into a three-dimensional network. The dichloromethane solvent molecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent molecule has a crystallographically imposed centre of symmetry.
[1,2-Bis(diphenylphosphanyl)ethane-κ2P,P']{2-[(4-nitrobenzoylmethyl)diphenyl_ phosphanyl]phenyl-κ2C,C'}palladium(II)trifluoromethanesulfonate―dichlorome_ thane―n-hexane (1/1/0.5) / Rizzoli, Corrado; K., Karami; F., Borzooie. - In: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. - ISSN 1600-5368. - E67:(2011), pp. m416-m417. [10.1107/S1600536811008075]
[1,2-Bis(diphenylphosphanyl)ethane-κ2P,P']{2-[(4-nitrobenzoylmethyl)diphenyl_ phosphanyl]phenyl-κ2C,C'}palladium(II)trifluoromethanesulfonate―dichlorome_ thane―n-hexane (1/1/0.5)
RIZZOLI, Corrado
;
2011-01-01
Abstract
In the cation of the title compound, [Pd(C26H19NO3P)(C26H24P2)]CF3O3S center dot CH2Cl2 center dot 0.5C(6)H(14), the PdII atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC3P and PdC2P2 five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, intermolecular C-H...O hydrogen bonds link cations and anions into a three-dimensional network. The dichloromethane solvent molecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent molecule has a crystallographically imposed centre of symmetry.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
