Transition metals can be used for shaping and electronically enriching the calix[4]arene cavity; in this approach, the pi-basic cavities can be adapted to alkali-metal cation complexation in a very hydrophobic environment and these cations can even be transferred into aliphatic hydrocarbons; the eta(6)-arene-alkali-metal cation interaction is structurally elucidated.
Shaping the Cavity of Calix[4]arene Using Transition Metals and Binding Alkali-Metal Cations Inside the Cavity: the Relevance of the Alkali-Metal Cation-Arene Interaction / A., Zanotti Gerosa; E., Solari; L., Giannini; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (1997), pp. 183-184. [10.1039/a606826j]
Shaping the Cavity of Calix[4]arene Using Transition Metals and Binding Alkali-Metal Cations Inside the Cavity: the Relevance of the Alkali-Metal Cation-Arene Interaction
RIZZOLI, Corrado
1997-01-01
Abstract
Transition metals can be used for shaping and electronically enriching the calix[4]arene cavity; in this approach, the pi-basic cavities can be adapted to alkali-metal cation complexation in a very hydrophobic environment and these cations can even be transferred into aliphatic hydrocarbons; the eta(6)-arene-alkali-metal cation interaction is structurally elucidated.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
