The reaction. of a Ti-Me species with carbon monoxide occurred with the complete cleavage of the C-O bond and formation of the Ti=O unit, while the [Me-C] fragment homologated a pyrrole to a 4-methylpyridine ring within the meso-octaethyl tris(pyrrole)mono(pyridine) macrocycle.
Binding of a meso-Octaethyl Tris(pyrrole) Mono(pyridine) Ligand to Titanium(III) and Titanium(IV): a Monomeric Titanium(IV) Oxo Bis(pyridine) Bis(pyrrole) Complex Derived from the C O Bond Cleavage of Carbon Monoxide / R., Crescenzi; E., Solari; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 15:(1996), pp. 5456-5458. [10.1021/om960208m]
Binding of a meso-Octaethyl Tris(pyrrole) Mono(pyridine) Ligand to Titanium(III) and Titanium(IV): a Monomeric Titanium(IV) Oxo Bis(pyridine) Bis(pyrrole) Complex Derived from the C O Bond Cleavage of Carbon Monoxide
RIZZOLI, Corrado
1996-01-01
Abstract
The reaction. of a Ti-Me species with carbon monoxide occurred with the complete cleavage of the C-O bond and formation of the Ti=O unit, while the [Me-C] fragment homologated a pyrrole to a 4-methylpyridine ring within the meso-octaethyl tris(pyrrole)mono(pyridine) macrocycle.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
