The title compound was synthesized and characterized by conventional methods and its X-ray crystal structure was determined. The complex crystallizes in the monoclinic space group C2/c with eight formula units in a cell of dimensions: a = 36.714(4), b = 15.746(2), c = 12.337(2) Angstrom; beta = 102.9(1)degrees. The structure is built up by alternate layers of octahedral [Ni(phen)(3)](2+) cations and perchlorate anions with water molecules which run in the direction of the a axis nearly parallel to the be plane.
Synthesis, Characterization, and X-Ray Crystal Structure of tris(1,10-phenanthroline)nickel(II) perchlorate hemihydrate / L., Abdel Rahman; Battaglia, Luigi Pietro; Rizzoli, Corrado; Sgarabotto, Paolo. - In: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY. - ISSN 1074-1542. - 25:(1995), pp. 629-632. [10.1007/BF01665968]
Synthesis, Characterization, and X-Ray Crystal Structure of tris(1,10-phenanthroline)nickel(II) perchlorate hemihydrate
BATTAGLIA, Luigi Pietro;RIZZOLI, Corrado;SGARABOTTO, Paolo
1995-01-01
Abstract
The title compound was synthesized and characterized by conventional methods and its X-ray crystal structure was determined. The complex crystallizes in the monoclinic space group C2/c with eight formula units in a cell of dimensions: a = 36.714(4), b = 15.746(2), c = 12.337(2) Angstrom; beta = 102.9(1)degrees. The structure is built up by alternate layers of octahedral [Ni(phen)(3)](2+) cations and perchlorate anions with water molecules which run in the direction of the a axis nearly parallel to the be plane.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
