The solvent-dependent reassembling of a conventional dimeric [Ti-O-Ti] unit into a chainlike titanoxane under ionization conditions is reported. The titanoxane is the polymeric form of the tetrameric sequence [Ti=O-Ti-O-Ti-O=Ti] containing both the titanyl unit and the mu-oxo dimer, polymerization being achieved by a sharing of the oxygen atoms from the Schiff base ligand.
Linear Titanoxane via the Assembling of Bridging and Terminal Oxo-Titanium(IV) Fragments / E., Gallo; E., Solari; F., Franceschi; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - 34:(1995), pp. 2495-2496. [10.1021/ic00114a003]
Linear Titanoxane via the Assembling of Bridging and Terminal Oxo-Titanium(IV) Fragments
RIZZOLI, Corrado
1995-01-01
Abstract
The solvent-dependent reassembling of a conventional dimeric [Ti-O-Ti] unit into a chainlike titanoxane under ionization conditions is reported. The titanoxane is the polymeric form of the tetrameric sequence [Ti=O-Ti-O-Ti-O=Ti] containing both the titanyl unit and the mu-oxo dimer, polymerization being achieved by a sharing of the oxygen atoms from the Schiff base ligand.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
