Both reduction and aryl/alkylation are involved in the reactions of aryl and alkyl Grignard reagents with the terminal (imido)vanadium(V) complex [ArNVCl3] to form diamagnetic cyclodivanadazene type species, [(μ-p-MeC6H4N)2V2R4] (R = CH2Ph, 2,4,6- Me3C6H2).
Cyclodivanadazene Alkyl and Aryl Complexes / G. A., Solan; P. G., Cozzi; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 13:(1994), pp. 2572-2574. [10.1021/om00019a012]
Cyclodivanadazene Alkyl and Aryl Complexes
RIZZOLI, Corrado
1994-01-01
Abstract
Both reduction and aryl/alkylation are involved in the reactions of aryl and alkyl Grignard reagents with the terminal (imido)vanadium(V) complex [ArNVCl3] to form diamagnetic cyclodivanadazene type species, [(μ-p-MeC6H4N)2V2R4] (R = CH2Ph, 2,4,6- Me3C6H2).File in questo prodotto:
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