Two short VN bonds and a long NN bond, as well as a sodium atom that is situated in the cavity created by the VNNV unit and two mesityl (mes) ligands are the intriguing characteristics of the anion of complex 1. It is formed by the reduction of [V(mes)3(thf)] with Na under N2 and on protonation yields NH3 and N2H4. Two mes ligands at both V and V′ are omitted from the picture shown on the right.
Fixation and Reduction of Dinitrogen by Vanadium(II) and Vanadium(III): Synthesis and Structure of Dinitrogenmesitylvanadium Complexes / R., Ferguson; E., Solari; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - 32:(1993), pp. 396-397. [10.1002/anie.199303961]
Fixation and Reduction of Dinitrogen by Vanadium(II) and Vanadium(III): Synthesis and Structure of Dinitrogenmesitylvanadium Complexes
RIZZOLI, Corrado
1993-01-01
Abstract
Two short VN bonds and a long NN bond, as well as a sodium atom that is situated in the cavity created by the VNNV unit and two mesityl (mes) ligands are the intriguing characteristics of the anion of complex 1. It is formed by the reduction of [V(mes)3(thf)] with Na under N2 and on protonation yields NH3 and N2H4. Two mes ligands at both V and V′ are omitted from the picture shown on the right.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
