p-tert-Butylcalix[4]arene has been converted into the corresponding tetra (diphenylphosphinite) derivative which has a cone conformation; reaction with [Fe(CO)3(η2-C8H14)2] led to binding of two Fe(CO)3 units, as confirmed by X-ray analysis, at the surface provided by the four trivalent phosphorus donors.
A Novel Class of Polyphosphorus Donor Ligands based on a Calix[n]arene Skeleton: Structural Chracterization of a Dinuclear Iron (0) Complex / D., Jacoby; C., Floriani; A., Chiesi Villa; Rizzoli, Corrado. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - (1993), pp. 813-814. [10.1039/DT9930000813]
A Novel Class of Polyphosphorus Donor Ligands based on a Calix[n]arene Skeleton: Structural Chracterization of a Dinuclear Iron (0) Complex
RIZZOLI, Corrado
1993-01-01
Abstract
p-tert-Butylcalix[4]arene has been converted into the corresponding tetra (diphenylphosphinite) derivative which has a cone conformation; reaction with [Fe(CO)3(η2-C8H14)2] led to binding of two Fe(CO)3 units, as confirmed by X-ray analysis, at the surface provided by the four trivalent phosphorus donors.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
